N. Keller et al., NIO ALPHA-FE2O3 MULTILAYERS PREPARED BY PLD - A MODEL SYSTEM FOR MAGNETIC STUDY OF INTERDIFFUSION/, IEEE transactions on magnetics, 34(4), 1998, pp. 837-839
We prepared multilayer Alms based on NiO and alpha Fe2O3 by pulsed las
er ablation. In these too NiO/alpha Fe2O3 and alpha Fe2O3/NiO multilay
ers, interdiffusion leads to the formation of the nickel ferrite NaFe2
O4 at the interfaces. Its ferrimagnetism provides a local probe on the
admixture of the antiferromagnetic oxides NiO and alpha Fe2O3 which i
s macroscopically measurable. We performed magnetization, torque and m
agneto-optical measurements on the multilayer samples. Surprisingly, a
n oscillation of the total magnetic moment rm as a function of the num
ber of interfaces was observed. The oscillation of m reverses when the
succession of NaO/alpha Pe(2)O(3) layers is inverted to alpha Fe2O3/N
iO multilayers. This indicates a magnetical and structural nan equival
ence of the NiO/alpha Fe2O3 and the alpha Fe2O3/NiO interfaces. This o
scillation is observed in the magnetization, the Faraday effect and th
e coercive fields. Furthermore, Secondary Ion Mass Spectroscopy measur
ements (SIMS) on some NiO/alpha Fe2O3 samples showed a well formed mul
tilayer structure with pronounced interlayers. The presence of NiFe2O4
can be seen from transmission spectroscopy measurements which we perf
ormed on the alpha Fe2O3/NiO multilayers series.