A direct correlation between the lattice parameter and the saturation
magnetization, during the disordering (ball milling) and posterior reo
rdering (annealing) processes, has been found in Fe-40Al at.% compound
s. These results indicate that the paramagnetic-ferromagnetic-paramagn
etic transitions induced by ball milling and subsequent annealing coul
d be related to the changes in volume, and not only to nearest neighbo
rs effects as is commonly assumed. Moreover, these alloys have been fo
und to become spin glass at low temperatures, independently of their s
tructural state (ordered or disordered).