Techniques to identify odorous compounds and to determine their emissi
on rates from liquid wastes are described. Odorous compounds, or odora
nts, were analysed by GC-MS and odour concentration was measured by ol
factometry after being emitted from slurry under controlled environmen
tal conditions using a specially designed odour emission chamber. The
slurries were obtained from pigs fed commercial and reduced crude prot
ein diets and stored for 6 weeks, the effects of age and sex upon the
odours produced in the headspace of the chamber were evaluated. The ma
jor odorous compounds were identified as belonging to the sulphide, vo
latile fatty acid, phenolic and indolic chemical groups. The mean emis
sion rates from 200 litres of stirred slurry samples with a surface ar
ea of 1 m(2) using a wind speed of 4 m s(-1) were 1.35 million Odour U
nits min(-1) for odour and 214, 2.15, 0.21, 0.44, 0.068 and 0.02 mg mi
n(-1) for hydrogen sulphide, ammonia, phenol, 4-methyl phenol, 4-ethyl
phenol and indole respectively. Sex and sex/diet interaction effects
were demonstrated for emission rates. (C) 1998 SCI.