RATE COEFFICIENT FOR THE REACTION - BR-]BR-2+BRO(BR2O)

Authors
BURKHOLDER JB
Citation
Jb. Burkholder, RATE COEFFICIENT FOR THE REACTION - BR-]BR-2+BRO(BR2O), International journal of chemical kinetics, 30(8), 1998, pp. 571-576
Citations number
14
Categorie Soggetti
Chemistry Physical
Journal title
International journal of chemical kinetics → ACNP
ISSN journal
05388066
Volume
30
Issue
8
Year of publication
1998
Pages
571 - 576
Database
ISI
SICI code
0538-8066(1998)30:8<571:RCFTR->2.0.ZU;2-E
Abstract
The room temperature rate coefficient for the reaction Br + Br2O --> B r-2 + BrO (3) has been measured using the technique of pulse-laser pho tolysis with long-path transient absorption detection of the BrO react ion product. A value of k(3) = (2.0 +/- 0.5) x 10(-10) cm(3) molecule( -1) s(-1) was determined. The photolysis products of Br2O at 308 nm we re also examined. (C) 1998 John Wiley & Sons. Inc. Int J Chem Kinet 30 : 571-576. 1998.