ESTERIFICATION IN DRY MEDIA USING FERRIC PERCHLORATE ADSORBED ON SILICA-GEL

Citation
A. Parmar et al., ESTERIFICATION IN DRY MEDIA USING FERRIC PERCHLORATE ADSORBED ON SILICA-GEL, Synthetic communications, 28(15), 1998, pp. 2821-2826
Citations number
13
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00397911
Volume
28
Issue
15
Year of publication
1998
Pages
2821 - 2826
Database
ISI
SICI code
0039-7911(1998)28:15<2821:EIDMUF>2.0.ZU;2-Z
Abstract
Adsorption of Fe(ClO4)(3)(H2O)(6) onto chromatographic grade silica ge l in the presence of alcohol (to be used for esterification) produces a supported reagent, Fe(ClO4)(3)(ROH)(6)/SiO2. This reagent, has been found effective for the rapid and high yield of esters, on grinding in the presence of carboxylic acids using pestle and mortar in the solid state.