Development of the future fusion reactors requires structural material
s capable to withstand extreme operation conditions, including the exp
osure to 14 MeV neutrons and intense thermomechanical stresses. Furthe
rmore, material technologies such as welding and joining, tiling, prod
uction of components having unusual size and shape must also be develo
ped. Therefore the microstructural effects produced in such materials
by irradiation or thermomechanical tests must also be studied by suita
ble ''diagnostic'' techniques. In this work, after an introduction rec
alling the most critical material problems in fusion technology, sever
al results are reviewed concerning the characterization of fusion-rele
vant materials by using radiation-based techniques such as neutron and
X-ray scattering, positron annihilation and some other more common on
es.