,11-TETRAAZACYCLOTETRADECANE-KAPPA-N-4]COBALT(III) PERCHLORATE

Authors
PANNEERSELVAM K LU TH TUNG SF LIU GS CHI TY CHUNG CS
Citation
K. Panneerselvam et al., ,11-TETRAAZACYCLOTETRADECANE-KAPPA-N-4]COBALT(III) PERCHLORATE, Acta crystallographica. Section C, Crystal structure communications, 54, 1998, pp. 714-716
Citations number
11
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
54
Year of publication
1998
Part
6
Pages
714 - 716
Database
ISI
SICI code
0108-2701(1998)54:<714:,P>2.0.ZU;2-P
Abstract
The crystal and molecular structure of the title compound, [CoCl2(C14H 32N4)]ClO4, has been determined. The Co-III ion is six-coordinate with a distorted octahedral geometry consisting of the four N atoms of the macrocyclic ligand in equatorial positions and the two Cl atoms in ax ial positions. The tetradentate macrocyclic ligand adopts its most sta ble configuration, with two six-membered rings in chair conformations and two five-membered rings in gauche forms.