OBIS(2-[(PHENYLETHYLIMINO)-METHYL]PHENOL-O)TIN(IV)

Citation
Gy. Yeap et N. Ishizawa, OBIS(2-[(PHENYLETHYLIMINO)-METHYL]PHENOL-O)TIN(IV), Acta crystallographica. Section C, Crystal structure communications, 54, 1998, pp. 720-722
Citations number
14
Categorie Soggetti
Crystallography
ISSN journal
01082701
Volume
54
Year of publication
1998
Part
6
Pages
720 - 722
Database
ISI
SICI code
0108-2701(1998)54:<720:O>2.0.ZU;2-U
Abstract
A crystal of the title compound, [SnCl2(C4H9)(2)- (C15H15NO)(2)] was p repared and its structure determined as the 1:2 tin-Schiff base adduct with space group P (1) over bar. The planes of the two phenyl rings o f each Schiff base ligand were found to be almost perpendicular to eac h other and the ligand is coordinated to the Sn atom via the phenolic O atom. The ligand adopts a zwitterionic structure in which the H atom from the hydroxy group is strongly attached to the imine N atom, form ing an N-H ... O intramolecular hydrogen bond.