-BUTOXYCARBONYLAMINO)-4-PYRIDYL]-TRIMETHYLTIN(IV), A TETRAORGANOTIN COMPOUND CONTAINING AN UNEXPECTED INTRAMOLECULAR SN-CENTER-DOT-CENTER-DOT-CENTER-DOT-O INTERACTION

Authors
CROUS R HOLZAPFEL CW KRUGER GJ
Citation
R. Crous et al., -BUTOXYCARBONYLAMINO)-4-PYRIDYL]-TRIMETHYLTIN(IV), A TETRAORGANOTIN COMPOUND CONTAINING AN UNEXPECTED INTRAMOLECULAR SN-CENTER-DOT-CENTER-DOT-CENTER-DOT-O INTERACTION, Acta crystallographica. Section C, Crystal structure communications, 54, 1998, pp. 760-762
Citations number
25
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
54
Year of publication
1998
Part
6
Pages
760 - 762
Database
ISI
SICI code
0108-2701(1998)54:<760:-ATC>2.0.ZU;2-W
Abstract
The configuration about the Sn centre in the title compound, [Sn(CH3)( 3)(C10H13N2O2)], is intermediate between tetrahedral and trigonal bipy ramidal. A weak intramolecular Sn ... O(carbonyl) interaction of 3.070 (3) Angstrom gives rise to an intramolecular six-membered chelate ring , formed through the carbonyl O atom; this is a unique feature of tetr aorganotin compounds. The title compound was prepared by consecutive r eaction of 3-(tert-butoxycarbonylamino)pyridine with n-butyllithium an d trimethyltin chloride.