(+ ,7-DIHYDRO-1,6,11-TRIMETHYL-5H-DIBENZ[C,E]AZEPINE/

Authors
MRVOSSERMEK D LONCARTOMASKOVIC L HERGOLDBRUNDIC A MINTAS M NAGL A
Citation
D. Mrvossermek et al., (+ ,7-DIHYDRO-1,6,11-TRIMETHYL-5H-DIBENZ[C,E]AZEPINE/, Acta crystallographica. Section C, Crystal structure communications, 54, 1998, pp. 877-879
Citations number
30
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
54
Year of publication
1998
Part
6
Pages
877 - 879
Database
ISI
SICI code
0108-2701(1998)54:<877:(,>2.0.ZU;2-5
Abstract
In the title compound, C17H19N, the central seven-membered azepine rin g adopts a twisted-boat conformation. The molecule exhibits a huge dev iation from planarity by rotation of the two fused ortho-methyl-substi tuted phenyl rings around the central C12-C14 single bond. The dihedra l angle between the planes of these two rings amounts to 56.05(4)degre es, with a cisoid arrangement around the C12-C14 bond. Because of this non-planarity, the molecule is axially chiral.