J. Karwowski et al., MOMENTS OF ENERGY-LEVEL DISTRIBUTIONS IN VIBRATIONAL-SPECTRA, Journal of physics. A, mathematical and general, 26(20), 1993, pp. 5581-5593
Expressions for moments of the spectral density distribution of a syst
em described by a non-symmetric N-particle Hamiltonian are derived. In
particular, this kind of Hamiltonian may represent N coupled oscillat
ors; then its spectrum models the vibrational spectrum of a molecule.
It is assumed that the Hamiltonian is defined in a finite-dimensional
space formed by products of orthogonal eigenstates of some one-body Ha
miltonians. Possible applications of the formalism are briefly discuss
ed.