MOMENTS OF ENERGY-LEVEL DISTRIBUTIONS IN VIBRATIONAL-SPECTRA

Citation
J. Karwowski et al., MOMENTS OF ENERGY-LEVEL DISTRIBUTIONS IN VIBRATIONAL-SPECTRA, Journal of physics. A, mathematical and general, 26(20), 1993, pp. 5581-5593
Citations number
30
Categorie Soggetti
Physics
ISSN journal
03054470
Volume
26
Issue
20
Year of publication
1993
Pages
5581 - 5593
Database
ISI
SICI code
0305-4470(1993)26:20<5581:MOEDIV>2.0.ZU;2-9
Abstract
Expressions for moments of the spectral density distribution of a syst em described by a non-symmetric N-particle Hamiltonian are derived. In particular, this kind of Hamiltonian may represent N coupled oscillat ors; then its spectrum models the vibrational spectrum of a molecule. It is assumed that the Hamiltonian is defined in a finite-dimensional space formed by products of orthogonal eigenstates of some one-body Ha miltonians. Possible applications of the formalism are briefly discuss ed.