Vm. Pergamenshchik, K-13 TERM AND EFFECTIVE BOUNDARY-CONDITION FOR THE NEMATIC DIRECTOR, Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics, 58(1), 1998, pp. 16-19
We consider the problem of including the divergence term K(13)del[n(de
l n)] in the macroscopic theory of a nematic liquid crystal. The orien
tation of the bulk director is shown to be determined by the standard
Euler Lagrange equation with an effective boundary condition which ass
umes a smooth vanishing of the nematic density at the surface and inco
rporates additional subsurface deformations. This boundary condition i
mplies that, in three dimensions, the K-13 term does not reduce to an
anchoring term.