Cm. Liao et al., EXPOSURE ASSESSMENT MODEL FOR ODOR CAUSING VOCS VOLATILIZATION FROM STORED PIG SLURRY, Journal of environmental science and health. Part B. Pesticides, food contaminants, and agricultural wastes, 33(4), 1998, pp. 457-486
A mathematical model taking into account source depletion with time an
d the actual thickness of manure layer was derived to evaluate indoor
inhalation exposure dynamics to three selected odor causing volatile o
rganic compounds (VOC-odors) of p-cresol, toluene, and xylene volatili
zation from stored pig slurry. The model assumes that pig slurry is un
disturbed and the VOC-odors released in a contaminated layer and trans
ported through a clean layer as well as a manure-air interface boundar
y. The model simulates time-dependent volatilization, the depletion of
source contaminant via both volatilization and degradation, and could
be used with a contaminated zone of finite thickness. For a given VOC
-odor, the predicted total exposure and resulting manure cleanup crite
ria can be a large variability depending on the model whether a finite
or infinite manure layer thickness was considered. Results obtained f
rom model comparisons suggest that the model incorporating depth-varyi
ng of manure layer and contaminant source depletion is more suitable t
o evaluate the VOC-odor exposure dynamics in swine housing bioclimate.