NEW HOMOCHIRAL CYCLIC DIOL LIGANDS FOR TITANIUM ALKOXIDE CATALYZED PHOSPHONYLATION OF ALDEHYDES

Authors
GROANING MD ROWE BJ SPILLING CD
Citation
Md. Groaning et al., NEW HOMOCHIRAL CYCLIC DIOL LIGANDS FOR TITANIUM ALKOXIDE CATALYZED PHOSPHONYLATION OF ALDEHYDES, Tetrahedron letters, 39(31), 1998, pp. 5485-5488
Citations number
45
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
39
Issue
31
Year of publication
1998
Pages
5485 - 5488
Database
ISI
SICI code
0040-4039(1998)39:31<5485:NHCDLF>2.0.ZU;2-1
Abstract
An investigation of the structural effects of chiral diol ligands on t he enantioselectivity of phosphorylation was performed. Cyclic diols, and cyclohexanediol in particular, were identified as effective ligand s for titanium alkoxide catalyzed asymmetric phosphorylation. (C) 1998 Elsevier Science Ltd. All rights reserved.