ASYMMETRIC-SYNTHESIS OF A NEW CYLINDRICALLY CHIRAL AND AIR-STABLE FERROCENYLDIPHOSPHINE AND ITS APPLICATION TO RHODIUM-CATALYZED ASYMMETRICHYDROGENATION

Authors
KANG J LEE JH AHN SH CHOI JS
Citation
J. Kang et al., ASYMMETRIC-SYNTHESIS OF A NEW CYLINDRICALLY CHIRAL AND AIR-STABLE FERROCENYLDIPHOSPHINE AND ITS APPLICATION TO RHODIUM-CATALYZED ASYMMETRICHYDROGENATION, Tetrahedron letters, 39(31), 1998, pp. 5523-5526
Citations number
30
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
39
Issue
31
Year of publication
1998
Pages
5523 - 5526
Database
ISI
SICI code
0040-4039(1998)39:31<5523:AOANCC>2.0.ZU;2-2
Abstract
A novel, cylindrically chiral air-stable ferrocenyldiphosphine ligand has been synthesized and its rhodium complexes have been applied to as ymmetric hydrogenation. High reactivity and selectivity have been real ized in hydrogenation of various dehydroamino acid derivatives. (C) 19 98 Elsevier Science Ltd. All rights reserved.