ELECTROPHILIC REACTIONS OF TRIADAMANTYLATED CALIX[4]ARENES AT THE UPPER RIM

Authors
KOVALEV V SHOKOVA E LUZIKOV Y
Citation
V. Kovalev et al., ELECTROPHILIC REACTIONS OF TRIADAMANTYLATED CALIX[4]ARENES AT THE UPPER RIM, Synthesis, (7), 1998, pp. 1003-1008
Citations number
29
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthesis → ACNP
ISSN journal
00397881
Issue
7
Year of publication
1998
Pages
1003 - 1008
Database
ISI
SICI code
0039-7881(1998):7<1003:EROTCA>2.0.ZU;2-E
Abstract
Chemical transformations of partially adamantylated calix[4]arenes at the upper rim are described. Starting from triadamantylated calix[4]ar ene, it is possible to obtain adamantane-containing macrocycles with f ormyl, acyl, sulfo, ate, 3-substituted 1-adamantyl, and dialkylaminome thyl groups at the upper rim. Synthesis of a new type of double adaman tane containing calix[4]arenes is also reported.