SOLVENT EFFECTS ON THE PIEZOCHROMISM OF MOLYBDENUM(IV) AND TUNGSTEN(IV) ANIONS [M(CN)(3)O(DIIMINE)](-)

Authors
NOWICKA B BURGESS J PARSONS SA SAMOTUS A SZKLARZEWICZ J
Citation
B. Nowicka et al., SOLVENT EFFECTS ON THE PIEZOCHROMISM OF MOLYBDENUM(IV) AND TUNGSTEN(IV) ANIONS [M(CN)(3)O(DIIMINE)](-), Transition metal chemistry, 23(3), 1998, pp. 317-319
Citations number
18
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Transition metal chemistry
ISSN journal
03404285 → ACNP
Volume
23
Issue
3
Year of publication
1998
Pages
317 - 319
Database
ISI
SICI code
0340-4285(1998)23:3<317:SEOTPO>2.0.ZU;2-F
Abstract
Solvatochromism of the [Mo(CN)(3)O(phen)](-) ion has been studied. Sol vent effects on pressure dependence (up to 1.25 kbar) of wavelengths o f maximum absorption for charge-transfer bands of several molybdenum(I V) and tungsten(IV) complexes, [M(CN)(3)O(diimine)](-)(M = Mo or W), a re described. The effects of applied pressure are larger for less pola r unstructured solvents than for highly polar hydrogen-bonded solvents .