GaAs (100) substrates were exposed to the helicon-wave excited N-2-O-2
-Ar plasma without and with substrate heating at 200 degrees C. The ox
ide dominantly composed of Ga2O3 and As2O3, was grown on the GaAs subs
trate using this technique. The chemical composition of this oxide was
highly uniform along the thickness of the oxide film. Relatively good
capacitance-voltage (C-V) characteristics were obtained. X-ray photoe
lectron spectroscopic data indicated that gallium nitride (GaN) bonds
were formed at the oxide/GaAs interface only with both substrate heati
ng and post-thermal annealing at 200 degrees C for 30 min in a nitroge
n ambient. The formation of the GaN/GaAs interface improved the C-V ch
aracteristics to some extent.