Various methods have been used worldwide for measuring the solubility
of phosphate rock (PR) and fertilizers containing PR. In this review,
chemical, mineralogical, and physical factors affecting various measur
ements of PR solubility are discussed. The most important factors are
(1) PR solubility expression, (2) mineralogical composition of PR, (3)
free carbonate (calcite dolomite) effect, (4) effect of apatite cryst
allinity and cementing of apatite with silica, and (5) effect of monoc
alcium phosphate and gypsum in the mixture of PR and TSP or SSP.