SEQUENCED REACTIONS WITH SAMARIUM(II) IODIDE, INTERMOLECULAR KETYL-OLEFIN COUPLING INTRAMOLECULAR NUCLEOPHILIC ACYL SUBSTITUTION FOR THE PREPARATION OF 6-MEMBERED, 7-MEMBERED, AND 8-MEMBERED CARBOCYCLES/

Authors
MOLANDER GA SONO M
Citation
Ga. Molander et M. Sono, SEQUENCED REACTIONS WITH SAMARIUM(II) IODIDE, INTERMOLECULAR KETYL-OLEFIN COUPLING INTRAMOLECULAR NUCLEOPHILIC ACYL SUBSTITUTION FOR THE PREPARATION OF 6-MEMBERED, 7-MEMBERED, AND 8-MEMBERED CARBOCYCLES/, Tetrahedron, 54(32), 1998, pp. 9289-9302
Citations number
29
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
54
Issue
32
Year of publication
1998
Pages
9289 - 9302
Database
ISI
SICI code
0040-4020(1998)54:32<9289:SRWSII>2.0.ZU;2-0
Abstract
A samarium(II) iodide-promoted sequence consisting of an intermolecula r ketyl-olefin coupling followed by an intramolecular nucleophilic acy l substitution is described. This process leads to functionalized six- to eight-membered monocyclic and bicyclic ring systems in moderate to good yields. (C) 1998 Elsevier Science Ltd. All rights reserved.