SYNTHESIS OF VARIOUSLY SUBSTITUTED ALLENEDIYNES AND THEIR COBALT (I)-MEDIATED [2+2+2] CYCLOADDITION REACTIONS

Authors
LLERENA D BUISINE O AUBERT C MALACRIA M
Citation
D. Llerena et al., SYNTHESIS OF VARIOUSLY SUBSTITUTED ALLENEDIYNES AND THEIR COBALT (I)-MEDIATED [2+2+2] CYCLOADDITION REACTIONS, Tetrahedron, 54(32), 1998, pp. 9373-9392
Citations number
49
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
54
Issue
32
Year of publication
1998
Pages
9373 - 9392
Database
ISI
SICI code
0040-4020(1998)54:32<9373:SOVSAA>2.0.ZU;2-D
Abstract
Syntheses of variously substituted allenediynes where the allene moiet y is at the terminal or internal position are described. Their cobalt( I)-mediated [2+2+2] cycloaddition reactions led to the corresponding e ta(4)-complexed tricyclic compounds; the regioselectivity of these cyc lizations depending on the substitution and the position of the allene is discussed. (C) 1998 Elsevier Science Ltd. Ali rights reserved.