RUCL3 CATALYZES ALDOL CONDENSATIONS OF ALDEHYDES AND KETONES

Citation
N. Iranpoor et F. Kazemi, RUCL3 CATALYZES ALDOL CONDENSATIONS OF ALDEHYDES AND KETONES, Tetrahedron, 54(32), 1998, pp. 9475-9480
Citations number
17
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00404020
Volume
54
Issue
32
Year of publication
1998
Pages
9475 - 9480
Database
ISI
SICI code
0040-4020(1998)54:32<9475:RCACOA>2.0.ZU;2-S
Abstract
Anhydrous RuCl3, catalyses the efficient cross aldol condensations of different ketones with various aromatic aldehydes in sealed tube under solvent free conditions without the occurrence of any self condensati ons. Regioselective self condensation reaction of some ketones and ald ehydes are also described. The catalytic effect of Ru(III) is shown by performing similar reactions under thermal conditions without catalys t. (C) 1998 Published by Elsevier Science Ltd. All rights reserved.