RADICAL CYCLIZATION FROM ALKENYL OXAZIRIDINES

Authors
BLACK DS EDWARDS GL LAAMAN SM
Citation
Ds. Black et al., RADICAL CYCLIZATION FROM ALKENYL OXAZIRIDINES, Tetrahedron letters, 39(32), 1998, pp. 5853-5856
Citations number
13
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
39
Issue
32
Year of publication
1998
Pages
5853 - 5856
Database
ISI
SICI code
0040-4039(1998)39:32<5853:RCFAO>2.0.ZU;2-#
Abstract
Some 6-oxa-1-azabicyclo[3.1.0]hexanes have been prepared by photoisome risation of alkenyl nitrone eaters and peracid oxidation of pyrrolines Their ring-opening reactions with iron(II) sulfate, tri-n-butyl tin h ydride and copper(I)triphenylphosphine chloride in many cases afford t he related pyrrolines, but some trans oxaziridines give products deriv ed from the trapping of aminyl radicals by the pendant alkenes. (C) 19 98 Elsevier Science Ltd. All rights reserved.