We have used Hartree calculations to investigate the electrical proper
ties of a sub-micron resonant tunnelling diode with an etched tear-sha
ped cross-section. Non-passivated surface states are shown to produce
a deep potential minimum near the centre of the tear drop. In the emit
ter accumulation layer, the conduction electrons screen this potential
minimum and move in an ideal hat-bottomed billiard with soft walls wh
ich generate a mixed stable-chaotic classical phase space. In the quan
tum well, the potential minimum is unscreened and there is a large ene
rgy splitting between the ground state and first excited state. The gr
ound state of the quantum well therefore provides an in-built spectros
copic probe of a wide range of quantized emitter states. Our studies h
ighlight the potential of tunnelling spectroscopy as an alternative to
parallel transport studies of chaotic billiards which only detect sta
tes near the Fermi level. (C) 1998 Elsevier Science B.V. All rights re
served.