SYNTHESIS AND CHARACTERIZATION OF [NBU4](4)[AG-2(MO5O13(OME)(4)(NO))(2)], A NOVEL POLYOXOMOLYBDATE COMPLEX WITH A SHORT AG-I-CENTER-DOT-CENTER-DOT-CENTER-DOT-AG-I DISTANCE

Authors
VILLANNEAU R PROUST A ROBERT F GOUZERH P
Citation
R. Villanneau et al., SYNTHESIS AND CHARACTERIZATION OF [NBU4](4)[AG-2(MO5O13(OME)(4)(NO))(2)], A NOVEL POLYOXOMOLYBDATE COMPLEX WITH A SHORT AG-I-CENTER-DOT-CENTER-DOT-CENTER-DOT-AG-I DISTANCE, Chemical communications, (14), 1998, pp. 1491-1492
Citations number
31
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
14
Year of publication
1998
Pages
1491 - 1492
Database
ISI
SICI code
1359-7345(1998):14<1491:SACO[>2.0.ZU;2-O
Abstract
In methanol, the defect nitrosylpolyoxomolybdate [Mo5O13(OMe)(4)(NO)]( 3-) reacts with Ag+ to give the complex [Ag-2{Mo5O13(OMe)(4)(NO)}(2)]( 4-) which displays attractive interactions between the two square-plan ar closed-shell Agr cations.