STRUCTURE EFFECTS OF WEAK-INTERACTIONS IN HETERODESMIC PI-COMPLEXES OF COPPER(I)

Authors
OLIJNIK VV
Citation
Vv. Olijnik, STRUCTURE EFFECTS OF WEAK-INTERACTIONS IN HETERODESMIC PI-COMPLEXES OF COPPER(I), Journal of structural chemistry, 39(1), 1998, pp. 80-87
Citations number
25
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Physical
Journal title
Journal of structural chemistry → ACNP
ISSN journal
00224766
Volume
39
Issue
1
Year of publication
1998
Pages
80 - 87
Database
ISI
SICI code
0022-4766(1998)39:1<80:SEOWIH>2.0.ZU;2-D
Abstract
Structural effects: disordering twinning, polymorphism, and morphotrop ism due to substitution of halide atoms are considered using the resul ts of X-ray diffraction analysis of 18 olefinic pi-complexes of Cu(I). These effects are associated with the heterodesmic character of compo unds, in particular, with weak interactions such as lengthened coordin ation bonds and hydrogen contacts.