ORDINARY ORGANIC-CRYSTAL CHEMISTRY - INTERPRETATION OF THE MOST PROBABLE HOMOMOLECULAR STRUCTURES

Citation
Pm. Zorkii et On. Zorkaya, ORDINARY ORGANIC-CRYSTAL CHEMISTRY - INTERPRETATION OF THE MOST PROBABLE HOMOMOLECULAR STRUCTURES, Journal of structural chemistry, 39(1), 1998, pp. 103-124
Citations number
19
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Physical
ISSN journal
00224766
Volume
39
Issue
1
Year of publication
1998
Pages
103 - 124
Database
ISI
SICI code
0022-4766(1998)39:1<103:OOC-IO>2.0.ZU;2-V
Abstract
For homomolecular organic crystals, most characteristic types of molec ular arrangement corresponding to most widespread structural classes a nd subclasses are named and interpreted. these characteristic structur al variants cover about 70% of crystal substances consisting of chemic ally identical molecules. Examples of crystal structures are cited to illustrate the structural laws of organic crystals; the structures are given as easily perceptible representations taken front the album ''S tructure of Organic Crystals. '' An important structural feature of or dinary molecular crystals is coexistence of molecules with four or two different orientations (64 and 28%, respectively). Basic notions and approaches of modem organic crystal chemistry are briefly defined.