R. Arreguinespinosa et al., COMPOSITION AND BIOSYNTHESIS IN THE SPONGE SPHECIOSPONGIA-VESPARIA, Journal of chemical technology and biotechnology, 72(3), 1998, pp. 245-248
The sterol composition of Spheciospongia vesparia from the Caribbean S
ea is reported. Three groups of sterols, Delta(5), Delta(0), Delta(5,7
) were found. The isolated 5 alpha,8 alpha-epidioxy sterols appeared t
o be predominantly, if not exclusively, artifacts. The auto-oxidation
of native Delta(5,7)-sterols to 5 alpha,8 alpha-epidioxy sterols has b
een investigated. A transformation of dietary Delta(5)-sterols to Delt
a(5,7)-sterols has been demonstrated in Spheciospongia vesparia. (C) 1
998 SCI.