CHEMICAL LIMITS TO FLAME INHIBITION

This paper deals with the ultimate limits of chemical contributions to flame inhibition. Particular attention is focussed on the inhibition cycles which regenerate the inhibitor. This leads to the definition of an idealized ''perfect'' inhibition cycle. It is demonstrated that fo r such an inhibitor in a stoichiometric methane/air flame, additive le vels in the 0.001-0.01 mole percent range will lead to a decrease in f lame velocity of approximately 30%. This efficiency corresponds roughl y to the observed behavior of metallic inhibitors such as iron pentaca rbonyl which is known to be as much as 2 orders of magnitude more effe ctive than currently used suppressants. This correspondence between th e behavior of a ''perfect inhibitor'' and iron carbonyl leads to the c onclusion that only gas-phase processes can account for its inhibitive power. (C) 1998 by The Combustion Institute.