SYNTHESIS AND CHARACTERIZATION OF POLY(AZOMETHINE)S WITH ROTAXANE ARCHITECTURE

Authors
SIMIONESCU CI GRIGORAS M FARCAS A STOLERU A
Citation
Ci. Simionescu et al., SYNTHESIS AND CHARACTERIZATION OF POLY(AZOMETHINE)S WITH ROTAXANE ARCHITECTURE, Macromolecular chemistry and physics, 199(7), 1998, pp. 1301-1306
Citations number
25
Categorie Soggetti
Polymer Sciences
Journal title
Macromolecular chemistry and physics → ACNP
ISSN journal
10221352
Volume
199
Issue
7
Year of publication
1998
Pages
1301 - 1306
Database
ISI
SICI code
1022-1352(1998)199:7<1301:SACOPW>2.0.ZU;2-8
Abstract
Poly(azometkine)s with rotaxane architecture were synthesized by means of solution polycondensation of terephthalaldehyde with 1,6-hexamethy lenediamine/ alpha- and beta-cyclodextrin adducts, and blocking of the chain ends with a bulky aromatic amine, i.e., p-aminophenyltriphenylm ethane. As compared with the polymer obtained in the absence of cyclod extrin, these polymers are more hygroscopic and soluble in polar solve nts while their IR, NMR and DSC data support the presence of cyclodext rins in the polymer chain.