RADICAL CHEMISTRY OF TERT-BUTYL HYDROPEROXIDE (TBHP) - PART 2 - STUDIES OF THE FE-II-TBHP MECHANISM

Authors
BARTON DHR LEGLOAHEC VN PATIN H
Citation
Dhr. Barton et al., RADICAL CHEMISTRY OF TERT-BUTYL HYDROPEROXIDE (TBHP) - PART 2 - STUDIES OF THE FE-II-TBHP MECHANISM, New journal of chemistry, 22(6), 1998, pp. 565-568
Citations number
23
Categorie Soggetti
Chemistry
Journal title
New journal of chemistry → ACNP
ISSN journal
11440546
Volume
22
Issue
6
Year of publication
1998
Pages
565 - 568
Database
ISI
SICI code
1144-0546(1998)22:6<565:RCOTH(>2.0.ZU;2-R
Abstract
By maintaining the iron catalyst in the ferrous [iron(II)] state, the oxidation chemistry of TBHP was dominated by the tert-butoxyl radical. Saturated hydrocarbons were readily oxidized.