Ms. Tsai et Ty. Tseng, CONDUCTION MECHANISM AND TEMPERATURE-DEPENDENT CURRENT-VOLTAGE IN (BA, SR)TIO3 THIN-FILMS, Journal of the Electrochemical Society, 145(8), 1998, pp. 2853-2860
Citations number
26
Categorie Soggetti
Electrochemistry,"Materials Science, Coatings & Films
RF magnetron sputtered (Ba, Sr)TiO3 (BST) thin films were deposited on
Pt/SiO substrate with various O-2/(O-2 + Ar) mixing ratios (OMR) rang
ing from 0 to 60%. Two possible conduction mechanisms of the BST thin
films, the Poole-Frenkel (PF) transport (bulk limited conduction) and
the Schottky emission (SE) (electrode limited conduction) were studied
. Experimental results indicated that the BST films prepared at low OM
R (0-25%) exhibit the SE mechanism dominated below the transition elec
tric field of 490 kV/cm and the PF transport mechanism dominated beyon
d 490 kV/cm; and while those prepared at high OMR (40-60%) display the
SE mechanism dominated both below and beyond the transition electric
field. The difference in dominant mechanism (bulk and electrode limite
d conduction) between films was ascribed to concentration variation of
the oxygen vacancy in the films.