FOURIER-TRANSFORM EMISSION-SPECTROSCOPY OF THE A(2)DELTA-CHI(2)PI TRANSITION OF SIH AND SID

Citation
Rs. Ram et al., FOURIER-TRANSFORM EMISSION-SPECTROSCOPY OF THE A(2)DELTA-CHI(2)PI TRANSITION OF SIH AND SID, Journal of molecular spectroscopy (Print), 190(2), 1998, pp. 341-352
Citations number
61
Categorie Soggetti
Spectroscopy,"Physics, Atomic, Molecular & Chemical
ISSN journal
00222852
Volume
190
Issue
2
Year of publication
1998
Pages
341 - 352
Database
ISI
SICI code
0022-2852(1998)190:2<341:FEOTAT>2.0.ZU;2-Y
Abstract
The emission spectra of the A(2)Delta-(XII)-I-2 transition of SiH and SiD have been observed at high resolution using a Fourier transform sp ectrometer. The molecules were excited in a Si hollow cathode lamp by passing a discharge through a mixture of Ne and a trace of H-2 or D-2. The present data, combined with the previous infrared vibration-rotat ion measurements, have been used to determine improved molecular const ants for the ground and excited states of Sill and SID. (C) 1998 Acade mic Press.