We have investigated the Wannier-Stark effect in GaAs/GaAl1-xAs superl
attices under electric fields by photocurrent spectroscopy measurement
s in the range of temperatures 10-300 K. The linewidth of the Oh Stark
-ladder exciton was found to increase significantly along with an incr
ease in peak intensity when the electric field increases. We present a
mechanism based on an enhanced interface roughness scattering of elec
tronic states due to Wannier-Stark localization in order to explain th
is increased broadening with electric field. This electric-field-relat
ed scattering mechanism will weaken the negative differential conducta
nce effects in superlattices predicted by Esaki and Tsu.