A SINGLE TRANSITION-STATE IN NUCLEOPHILIC AROMATIC-SUBSTITUTION - REACTION OF PHENOLATE IONS WITH 2-(4-NITROPHENOXY)-4,6-DIMETHOXY-1,3,5-TRIAZINE IN AQUEOUS-SOLUTION

Authors
HUNTER A RENFREW M TAYLOR JA WHITMORE JMJ WILLIAMS A
Citation
A. Hunter et al., A SINGLE TRANSITION-STATE IN NUCLEOPHILIC AROMATIC-SUBSTITUTION - REACTION OF PHENOLATE IONS WITH 2-(4-NITROPHENOXY)-4,6-DIMETHOXY-1,3,5-TRIAZINE IN AQUEOUS-SOLUTION, Perkin transactions. 2, (10), 1993, pp. 1703-1704
Citations number
23
Categorie Soggetti
Chemistry Physical","Chemistry Inorganic & Nuclear
Journal title
Perkin transactions. 2 → ACNP
ISSN journal
03009580
Issue
10
Year of publication
1993
Pages
1703 - 1704
Database
ISI
SICI code
0300-9580(1993):10<1703:ASTINA>2.0.ZU;2-4
Abstract
The absence of curvature in the Bronsted dependence for displacement o f 4-nitrophenolate ion from the title ether by phenolate ion nucleophi les with pK(a)s well below and above that of the leaving group is cons istent with a single step mechanism.