PRACTICAL RADICAL ADDITIONS UNDER MILD CONDITIONS USING 2,2'-AZOBIS(2,4-DIMETHYL-4-METHOXYVALERONITRILE) [V-70] AS AN INITIATOR

Authors
KITA Y GOTANDA K MURATA K SUEMURA M SANO A YAMAGUCHI T OKA M MATSUGI M
Citation
Y. Kita et al., PRACTICAL RADICAL ADDITIONS UNDER MILD CONDITIONS USING 2,2'-AZOBIS(2,4-DIMETHYL-4-METHOXYVALERONITRILE) [V-70] AS AN INITIATOR, Organic process research & development, 2(4), 1998, pp. 250-254
Citations number
24
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Medicinal
Journal title
Organic process research & development → ACNP
ISSN journal
10836160
Volume
2
Issue
4
Year of publication
1998
Pages
250 - 254
Database
ISI
SICI code
1083-6160(1998)2:4<250:PRAUMC>2.0.ZU;2-L
Abstract
Radical addition reactions of bromomalononitrile to various alkenes us ing 2,2'-azobis(2,4-dimethyl-4-methoxyvaleronitrile) (V-70) were exami ned. The advantages of V-70 which is an effective radical initiator at low temperature in contrast to the other azobis compounds are describ ed, Especially V-70L (the low melting point diastereomer) was found to be the best radical initiator.