FUNCTIONALIZED CHLOROENAMINES IN AMINOCYCLOPROPANE SYNTHESIS .11. BICYCLO[3.1.0]HEXANE DERIVATIVES PREFERRING A CHAIR CONFORMATION

Authors
VILSMAIER E FATH J TETZLAFF C MAAS G
Citation
E. Vilsmaier et al., FUNCTIONALIZED CHLOROENAMINES IN AMINOCYCLOPROPANE SYNTHESIS .11. BICYCLO[3.1.0]HEXANE DERIVATIVES PREFERRING A CHAIR CONFORMATION, Perkin transactions. 2, (10), 1993, pp. 1895-1900
Citations number
23
Categorie Soggetti
Chemistry Physical","Chemistry Inorganic & Nuclear
Journal title
Perkin transactions. 2 → ACNP
ISSN journal
03009580
Issue
10
Year of publication
1993
Pages
1895 - 1900
Database
ISI
SICI code
0300-9580(1993):10<1895:FCIAS.>2.0.ZU;2-6
Abstract
endo-endo-3,6-Diaminobicyclo[3.1.0]hexane species 6 prefer a chair con formation. This has been established by X-ray structure analysis of de rivative 6c and by H-1 and C-13 NMR spectroscopic analysis of compound s 6a and 6b. Intramolecular hydrogen bonding in 13, the monoammonium s alt of 6b, can change the conformational situation.