This paper reviews the use of pn-polymerised inorganic coagulants in w
ater and waste-water treatment, and discusses the removal of phosphoru
s by chemical precipitation and coagulation. Commonly used inorganic c
oagulants are aluminium or iron (IU) based salts, but a range of hydro
lysed Al/Fe species. and not re Al/Fe salt itself, are responsible for
the removal of impurities from water. By the development and use of p
olymeric inorganic coagulants, the coagulation performance can be impr
oved significantly in some cases. Chemical precipitation and coagulati
on in phosphorus removal are two different processes. with the former
related to the compound solubility acid the latter depending on the de
stabilisation-adsorption mechanism. Presently, there is uncertainty co
ncerning the mechanisms and overall performance of phosphorus removal
by pre-polymerised metal coagulants.