SYNTHESIS AND CRYSTAL-STRUCTURE OF [CU-2(OAC)(4)(NCME)(2)]CENTER-DOT-2MECN

Authors
GHASSEMZADEH M AGHAPOOR K NEUMULLER B
Citation
M. Ghassemzadeh et al., SYNTHESIS AND CRYSTAL-STRUCTURE OF [CU-2(OAC)(4)(NCME)(2)]CENTER-DOT-2MECN, Zeitschrift fur Naturforschung. B, A journal of chemical sciences, 53(7), 1998, pp. 774-776
Citations number
29
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur Naturforschung. B, A journal of chemical sciences → ACNP
ISSN journal
09320776
Volume
53
Issue
7
Year of publication
1998
Pages
774 - 776
Database
ISI
SICI code
0932-0776(1998)53:7<774:SACO[>2.0.ZU;2-F
Abstract
etrakis-mu-acetato-bis(acetonitrile-N)dicopper(II) bisacetonitrile (1) was synthesized and characterized by IR spectroscopy and by an X-ray structure determination [Space group P2(1)/n, Z = 2, lattice dimension s at -70 degrees C: a = 1063.2(1), b = 1018.4(1), c=1088.3(1) pm, beta = 101.59(1)degrees, R-1 = 0.048]. According to the structural data th e blue compound consists of centrosymmetric dimers [Cu-2(OAc)(4)(NCMe) (2)] and noncoordinated acetonitrile molecules.