Precipitates in GaN epilayers grown on sapphire substrates were invest
igated by atomic number contrast (ANC), wavelength-dispersive x-ray sp
ectrometry (WDS), energy-dispersive spectrometry (EDS), and cathodolum
inescence (CL) techniques. The results showed that the precipitates ar
e mainly composed of gallium and oxygen elements and distribute more s
parsely and inhomogeneously in [11 (2) over bar 0] directions in the s
ample grown on substrate nitridated for a longer period. Yellow lumine
scence intensity was imaged to be stronger in the precipitates. The re
sults suggest that the precipitates are formed on dislocations and gra
in boundaries by substituting oxygen onto the nitrogen site, and resul
t in the formations of deep levels nearby.