NMR ASSIGNMENTS AND CONFORMATION OF TARAXERENES

Authors
BATES RB JACOBSEN NE SETZER WN STESSMAN CC
Citation
Rb. Bates et al., NMR ASSIGNMENTS AND CONFORMATION OF TARAXERENES, Magnetic resonance in chemistry, 36(7), 1998, pp. 539-541
Citations number
11
Categorie Soggetti
Spectroscopy,Chemistry,"Chemistry Physical
Journal title
Magnetic resonance in chemistry → ACNP
ISSN journal
07491581
Volume
36
Issue
7
Year of publication
1998
Pages
539 - 541
Database
ISI
SICI code
0749-1581(1998)36:7<539:NAACOT>2.0.ZU;2-Y
Abstract
Complete H-1 and C-13 NMR chemical shift assignments were made for tar axerene from HMQC and HMBC spectra. Methyl proton shifts were assigned for 11 other taraxerenes. Molecular mechanics calculations and NMR ev idence supported the p-bromobenzyl acetylaleuritolate x-ray conformati on for taraxerenes in solution. (C) 1998 John Wiley & Sons, Ltd.