DIPHENYLBIS(2-PYRIDINETHIOLATO)TIN(IV)

Authors
SCHMIEDGEN R HUBER F PREUT H
Citation
R. Schmiedgen et al., DIPHENYLBIS(2-PYRIDINETHIOLATO)TIN(IV), Acta crystallographica. Section C, Crystal structure communications, 49, 1993, pp. 1735-1737
Citations number
11
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
49
Year of publication
1993
Part
10
Pages
1735 - 1737
Database
ISI
SICI code
0108-2701(1993)49:<1735:D>2.0.ZU;2-O
Abstract
The polyhedron around tin in the title compound is a distorted trapezo idal bipyramid with the two C(phenyl) atoms in axial positions. The tr apezoidal plane is formed by the two 2-pyridinethiolato residues which act as bidentate ligands with cis Sn-S and cis Sn-N bonds. Sn-N coord ination is indicated by short intramolecular Sn-N distances [Sn-N(1) = 2.636 (4), Sn-N(2) = 2.698 (4) angstrom]. The axial C atoms are shift ed towards the half-sphere occupied by two N atoms resulting in a C-Sn -C angle of 125.5 (1)-degrees. No short intermolecular interactions ar e observed.