N-FLUOROQUINUCLIDINIUM TRIFLUOROMETHANE-SULFONATE (TRIFLATE) - A NOVEL ELECTROPHILIC FLUORINATING AGENT

Authors
BANKS RE PRITCHARD RG SHARIF I
Citation
Re. Banks et al., N-FLUOROQUINUCLIDINIUM TRIFLUOROMETHANE-SULFONATE (TRIFLATE) - A NOVEL ELECTROPHILIC FLUORINATING AGENT, Acta crystallographica. Section C, Crystal structure communications, 49, 1993, pp. 1806-1807
Citations number
15
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
49
Year of publication
1993
Part
10
Pages
1806 - 1807
Database
ISI
SICI code
0108-2701(1993)49:<1806:NT(-AN>2.0.ZU;2-C
Abstract
The N-F bond length of 1.407 (6) angstrom in the title molecule is clo se to the value of 1.37 (2) angstrom found in romethyl-4-fluoro-1,4-di azoniabicyclo[2.2.2]octane bis(tetrafluoroborate) [Banks, Sharif & Pri tchard (1993). Acta Cryst. C49, 492-495]. Both these bonds are substan tially longer than those in NF4+.BF4-, which range from 1.265 (9) to 1 .321 (10) angstrom [Christie, Lind, Tborup, Russell, Fawcett & Bau (19 88). Inorg. Chem. 27, 2450-2454].