2-Amino-2-carboxyethylphosphinic acid exists as a zwitterion (2-ammoni
o-2-carboxyethylphosphinate) with anionic phosphinic, cationic alkylam
monium and neutral carboxyl groups. The P-C-C-C and P-C-C-N conformati
ons are gauche and trans, respectively. In contrast to 2-amino-2-carbo
xyethylphosphonic acid, intramolecular hydrogen bonding from ammonium
to phosphinic moieties does not occur. Each phosphinic O atom accepts
two intermolecular hydrogen bonds, as does the water molecule; every a
mmonium, carboxyl and water H atom participates.