2-AMINO-2-CARBOXYETHYLPHOSPHINIC ACID MONOHYDRATE

Citation
Ch. Schwalbe et al., 2-AMINO-2-CARBOXYETHYLPHOSPHINIC ACID MONOHYDRATE, Acta crystallographica. Section C, Crystal structure communications, 49, 1993, pp. 1826-1828
Citations number
17
Categorie Soggetti
Crystallography
ISSN journal
01082701
Volume
49
Year of publication
1993
Part
10
Pages
1826 - 1828
Database
ISI
SICI code
0108-2701(1993)49:<1826:2AM>2.0.ZU;2-D
Abstract
2-Amino-2-carboxyethylphosphinic acid exists as a zwitterion (2-ammoni o-2-carboxyethylphosphinate) with anionic phosphinic, cationic alkylam monium and neutral carboxyl groups. The P-C-C-C and P-C-C-N conformati ons are gauche and trans, respectively. In contrast to 2-amino-2-carbo xyethylphosphonic acid, intramolecular hydrogen bonding from ammonium to phosphinic moieties does not occur. Each phosphinic O atom accepts two intermolecular hydrogen bonds, as does the water molecule; every a mmonium, carboxyl and water H atom participates.