ENANTIOSELECTIVE N-ACETYLATION OF RACEMIC SECONDARY ALKYL AMINES WITHCHIRAL 2-ACETYLAMINO-2'-DIACETYLAMINO-1,1'-BINAPHTHYL

Authors
KONDO K KUROSAKI T MURAKAMI Y
Citation
K. Kondo et al., ENANTIOSELECTIVE N-ACETYLATION OF RACEMIC SECONDARY ALKYL AMINES WITHCHIRAL 2-ACETYLAMINO-2'-DIACETYLAMINO-1,1'-BINAPHTHYL, Synlett, (7), 1998, pp. 725-726
Citations number
22
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synlett → ACNP
ISSN journal
09365214
Issue
7
Year of publication
1998
Pages
725 - 726
Database
ISI
SICI code
0936-5214(1998):7<725:ENORSA>2.0.ZU;2-V
Abstract
The enantioselective N-acetylation of racemic secondary alkyl amines w ith chiral 2-acetylamino-2'-diacetylamino-1,1'-binaphthyl (2) is descr ibed. This N-acetylation with 2 was effective for 1-arylethylamine and phenylalanine benzyl ester to give the corresponding N-acetylamines w ith up to 48% ee.