SYNTHESIS OF HIGHLY FUNCTIONALIZED POLYCYCLICS VIA PD-CATALYZED INTRAMOLECULAR COUPLING OF ARYL VINYLIC HALIDES, NONCONJUGATED DIENES AND NUCLEOPHILES/
Xj. Han et Rc. Larock, SYNTHESIS OF HIGHLY FUNCTIONALIZED POLYCYCLICS VIA PD-CATALYZED INTRAMOLECULAR COUPLING OF ARYL VINYLIC HALIDES, NONCONJUGATED DIENES AND NUCLEOPHILES/, Synlett, (7), 1998, pp. 748-750
Aryl and vinylic iodides bearing a 2,5-cyclohexadienyl moiety readily
undergo sequential intramolecular/intermolecular Pd-catalyzed cross-co
upling with carbon and heteroatom nucleophiles to produce a wide varie
ty of diastereomerically pure polycyclic products in good to excellent
yields.