The use of synchrotron based x-ray microbeam fluorescence (mu-SYXRF) f
or the identification of relatively insoluble gas species in bubbles i
n glasses is presented. The nondestructive method of SYXRF allows the
in situ analysis of unopened inclusions with high spatial resolution a
nd low detection limits. The example is given of the analysis of the n
oble gas Xe and Mo and Rb in an aluminosilicate glass matrix. The use
of synchrotron based x-ray micro beam fluorescence for the nondestruct
ive identification and analysis of fluid inclusions (gas bubbles) in g
lasses is recommended for applications in the glass industry and geoch
emistry of fluids.