Advanced coal-fired combined-cycle power systems under development and
demonstration have the potential to increase generating efficiency to
approach 50%, reduce the cost of electricity by up to 20%, and meet s
tringent standards on emissions of SOx, NOx, fine particulates, and ai
r toxic metals. Integrated gasification combined-cycle, pressurized fl
uidized-bed combustion, and externally fired combined-cycle systems re
ly on different high-temperature combinations of heat exchange, gas fi
ltration, and sulfur capture to meet these requirements. The success o
f these systems when operated on low-rank coals depends importantly on
the behavior of the ash. Deposits were analyzed from the riser and di
sengager sections of an experimental transport reactor development uni
t (TRDU) operating on a high-calcium Belie Ayr, Wyoming, subbituminous
coal under gasification conditions for 107 cumulative hours, with sho
rt periods at oxidizing conditions during start-up and system upsets.
Deposits appeared to have formed by the cementing action of low-meltin
g-point calcium magnesium aluminosilicates derived from the finer coal
ash. Depending an deposit location, aerodynamic classification appear
ed to have affected the proportion of finer material derived from coal
ash to coarser particles from the zeolite-based start-up bed material
. Bridging deposits from a test candle filter were similar in chemical
composition to the finer ash. (C) 1998 Elsevier Science B.V. All righ
ts reserved.