R. Pikl et al., VIBRATIONAL-SPECTRA AND FACTOR GROUP-ANALYSIS OF MN(0.5-2X)CR2X(PO4)(3) -OR-EQUAL-TO-X-LESS-THAN-OR-EQUAL-TO-0.50)(X)TI(2), Vibrational spectroscopy, 16(2), 1998, pp. 137-143
Raman and infrared spectra of a series of phosphates Mn0.5+xTi2-2xCr2x
(PO4)(3) {0 less than or equal to x less than or equal to 0.5} have be
en recorded in crystalline state. Factor group analysis has been perfo
rmed for space group R (3) over bar (x = 0, 0.1, 0.15) and R (3) over
bar c (x = 0.25, 0.5) and assignments of the internal modes of the PO4
tetrahedra have been made. (C) 1998 Elsevier Science B.V. All rights
reserved.