STEREOCONTROLLED CYCLIZATION OF UNACTIVATED ALKENE ONTO CATIONIC DIENYL IRON TRICARBONYL SYSTEMS

Authors
PEARSON AJ ALIMARDANOV A PINKERTON AA FOUCHARD DM KIRSCHBAUM K
Citation
Aj. Pearson et al., STEREOCONTROLLED CYCLIZATION OF UNACTIVATED ALKENE ONTO CATIONIC DIENYL IRON TRICARBONYL SYSTEMS, Tetrahedron letters, 39(33), 1998, pp. 5919-5922
Citations number
14
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
39
Issue
33
Year of publication
1998
Pages
5919 - 5922
Database
ISI
SICI code
0040-4039(1998)39:33<5919:SCOUAO>2.0.ZU;2-C
Abstract
Treatment of pentadienol-Fe(CO)(3) complexes, having alkene functional ity in the side chain, with boron trifluoride, results in a stereospec ific cyclization by reaction of the alkene with a stabilized carbocati on intermediate; the stereochemical outcome was confirmed by X-ray str ucture determination of one of the products. (C) 1998 Elsevier Science Ltd. All rights reserved.